Subject: QD Chemistry
Year: 2020
Type: Article
Type: PeerReviewed
Title: SYNTHESIS AND CHARACTERIZATION OF RUTHENIUM (III) COMPLEXES WITH TRIDENTATE (ONO) SCHIFF BASES
Author: Dehari, Dije
Author: Jonuzi, Emir
Author: Dehari, Shefket
Author: Abduli, Shemsedin
Author: Abdija, Zulxhevat
Abstract: The reactions of Ru(III) chloride with tridentate dibasic Schiff bases (H2SB) gave anionic complexes of types [Ru(SB)2]-(Et)4N+. Schiff bases prepared from salicylaldehyde, 5-chlorosalicylaldehyde, and 5-bromosalicylaldehyde with 2-aminophenol. The anionic complexes have been prepared and precipitated with tetraethylammoniumbromide. New complexeshave been characterized based on elemental analyses, IR spectroscopy, UV-VIS spectroscopy, and ESI mass spectrometry. Measures of mass spectrometry with the method ESI show that the complexes are anionic and the calculated molecular mass of the corresponding anion complies with the molecular mass of the experimentally found complex anion. The results are in accord with an octahedral environment around the Ru (III) ion.
Publisher: University of Tetova
Relation: https://eprints.unite.edu.mk/601/
Identifier: oai:eprints.unite.edu.mk:601
Identifier: https://eprints.unite.edu.mk/601/1/3.pdfIdentifier: Dehari, Dije and Jonuzi, Emir and Dehari, Shefket and Abduli, Shemsedin and Abdija, Zulxhevat (2020) SYNTHESIS AND CHARACTERIZATION OF RUTHENIUM (III) COMPLEXES WITH TRIDENTATE (ONO) SCHIFF BASES. Journal of Natural Sciences and Mathematics of UT, 5 (9-10). pp. 31-36. ISSN 2671-3039
