Year: 2007
Type: Article
Title: Study of structural and electrochemical characteristics of Co-based hypo–hyper d-electrocatalysts for hydrogen evolution
Author: P. Paunovic, O. Popovski, A. Dimitrov, D. Slavkov, E. Lefterova, S. Hadzi Jordanov
Abstract: Structural and electrochemical characteristics of hypo–hyper d-electrocatalytic materials aimed for preparation of electrodes for hydrogen evolution were studied. The basic catalytic material was prepared of 10% amorphous Co (grain size <2 nm), 18% amorphous TiO2 and Vulcan XC-72, by sol–gel procedure. A number of modifications were applied aimed at improving the materials performances: (i) TiO2 was transformed into anatase by heating at 480 ◦C for 1 h, (ii) multiwalled carbon nanotubes (MWCNT) were used as a catalyst support instead of Vulcan XC-72 and (iii) Mo was added to Co phase in a quantity of 25 at.% (Mo:Co = 1:3). Both, material’s intrinsic catalytic activity and surface area were affected by these modifications. As a result, the electrocatalytic activity for hydrogen evolution was improved, e.g. transformation of TiO2 into anatase form lowers the HER overpotential (η) for 15mV at 60mAcm−2. Introduction of MWCNTs lowered η for 30mV, while addition of Mo to metallic phase for 40mV. The complete modification of all three catalyst’s components (10% MoCo3 + 18% anatase + MWCNTs) was the most effective with 60mV decrease of overpotential. Characterization was made by XRD, SEM, IR and XPS methods. Surface area was measured by means of cyclic voltammetry.
Publisher: Elsevier
Relation: Electrochimica Acta
Identifier: oai:repository.ukim.mk:20.500.12188/444
Identifier: http://hdl.handle.net/20.500.12188/444Identifier: 10.1016/j.electacta.2007.01.053
