Subject: Chemical sciences
Year: 2023
Type: Experiment
Type: NonPeerReviewed
Title: Regenerative Mechanism in Two-Step Diffusional EEC’ Mechanism in Square-Wave Voltammetry
Author: Gulaboski, Rubin
Abstract: The regenerative mechanism in two-step diffusional EEC’ mechanism associated to the product of second electrochemical step is studied theoretically under conditions of square-wave voltammetry. As many water-soluble redox enzymes commonly undergo electrochemical transformation in two consecutive electron transfer steps, the regeneration of the intermediate product via homogeneous chemical reaction of the last electrochemically generated product of the second electron transfer is a fundamental process to understand enzyme-substrate kinetics of such complex systems. This work gives entire MATHCAD simulation protocol of this complex mechanism in square-wave voltammetry.
Publisher:
Relation: https://eprints.ugd.edu.mk/32870/
Identifier: oai:eprints.ugd.edu.mk:32870
Identifier: https://eprints.ugd.edu.mk/32870/1/Regenerative%20Diffusional%20Mechanism%20in%20EEC%27-Gulaboski.pdfIdentifier: Gulaboski, Rubin (2023) Regenerative Mechanism in Two-Step Diffusional EEC’ Mechanism in Square-Wave Voltammetry. [Experiment] (Unpublished)
