Subject: Chemical sciences
Year: 2023
Type: Experiment
Type: NonPeerReviewed
Title: Practical Guidelines to Recognize Electrochemical Mechanisms with Coupled Chemical Reactions in Square-Wave Voltammetry
Author: Gulaboski, Rubin
Abstract: Although the square-wave voltammetry (SWV) is recognized as a leading member in the family of “Pulse” Voltammetric techniques, yet it is quite difficult for many experimentalists to recognize certain electrode mechanism simply from the features of obtained square-wave voltammograms. In this work, a series of theoretical square-wave voltammograms are presented, simulated for E, EC, CE and EC’ mechanisms. Voltammetric patterns presented in this work are calculated as a function of the chemical rate parameters, and they provide quite specific features that can be explored for identification of some one-step electrode mechanism coupled with defined chemical reaction. The voltammograms presented in this work can serve as a simple guideline for the students and for those with not enough knowledge in voltammetry.
Publisher:
Relation: https://eprints.ugd.edu.mk/32179/
Identifier: oai:eprints.ugd.edu.mk:32179
Identifier: https://eprints.ugd.edu.mk/32179/1/1-Guidelines%20to%20Recognize%20Electrochemical%20Mechanisms%20with%20Coupled%20Chemical%20Reactions%20in%20Square.pdfIdentifier: Gulaboski, Rubin (2023) Practical Guidelines to Recognize Electrochemical Mechanisms with Coupled Chemical Reactions in Square-Wave Voltammetry. [Experiment] (Unpublished)
