Subject: Chemical sciences
Year: 2023
Type: Dataset
Type: NonPeerReviewed
Title: EE Diffusional Mechanism in Square-Wave Voltammetry-MATHCAD Simulation Protocol
Author: Gulaboski, Rubin
Abstract: Physiologically, the consecutive two-step electrode mechanism often occurs when a stable intermediate is formed during the initial electron transfer. This intermediate can then undergo further electrochemical transformations. The enzymatic generation of numerous reactive oxygen species is actually a result of multi-step redox transformations taking place in various redox enzymes. In this study, a comprehensive MATHCAD simulation protocol is introduced, enabling the simulation of the two-step EE mechanism for fully water-soluble redox active compounds. Researchers can benefit from this simulation protocol to analyze the kinetics of both electron transfer steps in real experiments. The model presented in this study serves as a useful playground to understand this mechanism, even in systems with inverse electrode potentials. Originally, this model has been solved and presented by Komorsky-Lovric and M. Lovric and presented in J Electroanal Chem 660 (2011) 22-25, while we give here the entire simulation protocol in MATHCAD.
Publisher:
Relation: https://eprints.ugd.edu.mk/31826/
Identifier: oai:eprints.ugd.edu.mk:31826
Identifier: https://eprints.ugd.edu.mk/31826/1/2-step-EE%20Diffusional%20Mechanism%20in%20SWV-MATHCAD%20Simulation%20Protocol.pdfIdentifier: Gulaboski, Rubin (2023) EE Diffusional Mechanism in Square-Wave Voltammetry-MATHCAD Simulation Protocol. [Dataset] (Unpublished)
