Subject: Biological sciences
Subject: Chemical sciences
Subject: Physical sciences
Year: 2021
Type: Dataset
Type: NonPeerReviewed
Title: TWo-Step Protein-Film Voltammetry Coupled with Intermediate Reversible Chemical Step-MATHCAD Simulation File
Author: Gulaboski, Rubin
Abstract: Two-step electrode mechanisms coupled with intermediate reversible chemical reaction between both electron transfer step are common for many redox proteins. Protonation/deprotonation, for example, is a chemical step that bridges multielectron transfer in many redox proteins such as cytochromes, redox enzymes with quinone-moieties in their structures, and also some redox proteins with transient metals. We give the readers entire working MATHCAD protocol to simulate the redox chemistry of such systems in square-wave voltammetry. In this work, we are also focused on redox proteins with inverted potentials, while we provide diagnostic criteria to recognize such systems in square-wave voltammetry.
Publisher:
Relation: https://eprints.ugd.edu.mk/28232/
Identifier: oai:eprints.ugd.edu.mk:28232
Identifier: https://eprints.ugd.edu.mk/28232/1/Protein%20Film%20Voltammetry%20of%20ECrevE%20%20mechanism%20with%20Reversible%20Chemical%20Step.pdfIdentifier: Gulaboski, Rubin (2021) TWo-Step Protein-Film Voltammetry Coupled with Intermediate Reversible Chemical Step-MATHCAD Simulation File. [Dataset] (Unpublished)
