Subject: Basic medicine
Subject: Chemical sciences
Subject: Physical sciences
Year: 2021
Type: Dataset
Type: NonPeerReviewed
Title: Square-wave Voltammetric Theory of Two-Step Surface Electrode Mechanism Associated with Intermediate Irreversible Regenerative Chemical Reaction-SWV of Surface ECatE mechanism
Author: Gulaboski, Rubin
Abstract: For the first time, we present theoretical model of a two-step surface electrode mechanism, in which an irreversible regenerative chemical reaction is associated to the first electron transfer step. The abbreviation of this mechanism is "Surface ECatE mechanism". The model is solved under conditions of square-wave voltammetry (SWV). Model is relevant for many lipophilic redox enzymes, whose redox transformation takes place in two consecutive electron transfer steps. While we present several sets of specific voltammograms relevant to this mechanism, readers can explore the MATHCAD file for free to simulate different conditions at such systems. Experimental systems are found in many quinone-containing redox enzymes, such as FAD enzymes involved in the oxidative phosphorylation mechanism.
Publisher:
Relation: https://eprints.ugd.edu.mk/27974/
Identifier: oai:eprints.ugd.edu.mk:27974
Identifier: https://eprints.ugd.edu.mk/27974/1/SWV%20of%20Suurface%20ECatE%20mechanism%202021-Gulaboski.pdfIdentifier: Gulaboski, Rubin (2021) Square-wave Voltammetric Theory of Two-Step Surface Electrode Mechanism Associated with Intermediate Irreversible Regenerative Chemical Reaction-SWV of Surface ECatE mechanism. [Dataset] (Unpublished)
