Subject: Basic medicine
Subject: Biological sciences
Subject: Chemical sciences
Subject: Matematics
Subject: Physical sciences

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Year: 2003

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Type: Article
Type: PeerReviewed

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Title: The determination of standard Gibbs energies of transfer of cations across the nitrobenzene|water interface using a three-phase electrode

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Author: Scholz, Fritz
Author: Gulaboski, Rubin
Author: Caban, Karolina

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Abstract: A three-phase electrode consisting of a droplet of a nitrobenzene solution of iron(III) tetraphenyl porphyrine chloride (Fe(III)- TPP-Cl) attached to a graphite electrode and immersed in an aqueous electrolyte solution was applied to determine the standard Gibbs energies of transfer of cations between water and nitrobenzene. The reduction of Fe(III)-TPP-Cl prompts the transfer of the cations from the aqueous to the organic phase. The system is chemically and electrochemically reversible.

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Publisher:

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Relation: https://eprints.ugd.edu.mk/171/

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Identifier: oai:eprints.ugd.edu.mk:172
Identifier: https://eprints.ugd.edu.mk/171/1/__ugd.edu.mk_private_UserFiles_rubin.gulaboski_Desktop_GULABOSKI-MY%20pdf%20PUBLICATIONS_Trud%20cation%20transfer%20EC%202003%20final.pdf
Identifier: Scholz, Fritz and Gulaboski, Rubin and Caban, Karolina (2003) The determination of standard Gibbs energies of transfer of cations across the nitrobenzene|water interface using a three-phase electrode. Electrochemistry Communications, 5 (11). pp. 929-934. ISSN 13882481
Identifier: doi:10.1016/j.elecom.2003.09.005

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