Subject: Basic medicine
Subject: Biological sciences
Subject: Chemical sciences
Subject: Physical sciences
Year: 2003
Type: Article
Type: PeerReviewed
Title: Standard Gibbs energies of transfer of halogenate and pseudohalogenate ions, halogen substituted acetates, and cycloalkyl carboxylate anions at the water|nitrobenzene interface
Author: Gulaboski, Rubin
Author: Riedl, Kai
Author: Scholz, Fritz
Abstract: The previously introduced three-phase electrode technique was used to determine the Gibbs energies of transfer of ClO3 , BrO3 , IO3 , IO4 , OCN , SeCN , CN , N3 , halogen substituted acetate anions Z3 nCHnCOO (Z ¼ F,Cl,Br,I), and cycloalkyl carboxylate anions ((CH2)nCOO , n ¼ 3,. . .,7) at the water|nitrobenzene interface. Whereas the data for the small inorganic ions can easily be understood in terms of ion-dipole interactions, the data of the organic ions need consideration of charge delocalisation and its effect on the enthalpy and entropy of solvation.
Publisher:
Relation: https://eprints.ugd.edu.mk/164/
Identifier: oai:eprints.ugd.edu.mk:164
Identifier: https://eprints.ugd.edu.mk/164/1/__ugd.edu.mk_private_UserFiles_rubin.gulaboski_Desktop_GULABOSKI-MY%20pdf%20PUBLICATIONS_PCCP%20paper-2003.pdfIdentifier: Gulaboski, Rubin and Riedl, Kai and Scholz, Fritz (2003) Standard Gibbs energies of transfer of halogenate and pseudohalogenate ions, halogen substituted acetates, and cycloalkyl carboxylate anions at the water|nitrobenzene interface. Physical Chemistry Chemical Physics, 5 (6). pp. 1284-1289. ISSN 14639076
Identifier: doi:10.1039/b210356g
