Subject: Chemical sciences
Year: 2002
Type: Article
Type: PeerReviewed
Title: Quantification of the chiral recognition in electrochemically driven ion transfer across the interface water/chiral liquid
Author: Scholz, Fritz
Author: Gulaboski, Rubin
Author: Mirceski, Valentin
Author: Langer, Peter
Abstract: The electrochemically driven transfer of the chiral anions of D- and L-tryptophan across the interface water/chiral liquid (D- or Lmenthol) is stereoselective, and it can be used to determine quantitatively the difference in Gibbs energies for the solvation of chiral ions in chiral liquids. The ion transfer can be achieved in a three-phase arrangement where a droplet of the chiral liquid containing decamethylferrocene as the electroactive redox probe is attached to a graphite electrode immersed in the aqueous solution containing the chiral ions.
Publisher:
Relation: https://eprints.ugd.edu.mk/138/
Identifier: oai:eprints.ugd.edu.mk:138
Identifier: https://eprints.ugd.edu.mk/138/1/__ugd.edu.mk_private_UserFiles_rubin.gulaboski_Desktop_GULABOSKI-MY%20pdf%20PUBLICATIONS_chirality%20paper-Electrochem%20Commun%202002.pdfIdentifier: Scholz, Fritz and Gulaboski, Rubin and Mirceski, Valentin and Langer, Peter (2002) Quantification of the chiral recognition in electrochemically driven ion transfer across the interface water/chiral liquid. Electrochemistry Communications, 4 (8). pp. 659-662. ISSN 13882481
Identifier: doi:10.1016/S1388-2481(02)00410-1
